碘化鋅危險特性:
危險特性:具有腐蝕性。
健康危害:該品具有腐蝕性,能引起燒傷。吸入對鼻、喉和呼吸道有刺激作用。
環境危害:對環境有危害,對水體、土壤和大氣可造成污染。
燃爆危險:本品不燃。
碘化鋅操作處置和存儲:
操作注意事項: 密閉操作,全面通風。遠離火種、熱源等。搬運時要輕裝輕卸,放置包裝及容器損壞。配備相應品種和數量的消防器材及泄漏應急處理設備。
儲存注意事項: 儲存于陰涼、通風的密閉容器中。儲區應備有泄漏應急處理設備和合適的收容材料。
碘化鋅運輸注意事項:
運輸時運輸車輛應配備相應品種和數量的消防器材及泄漏應急處理設備。運輸途中應防曝曬、雨淋,防高溫。中途停留時應遠離火種、熱源、高溫區。
Product Identification
【Product Name】Zinc iodide ;碘化鋅
【CAS】10139-47-6
【Formula】ZnI2
【Molecular Weight】319.18
【EINECS】233-396-0
【Merck】12,10269
【Beilstein/Gmelin】9337 (G)
Physical and Chemical Properties
【Appearance】white hygroscopic crystals
【Melting Point】446℃
【Boiling Point】620℃
【Vapor Pressure】0.0108 (270℃)
【Density】4.74 g/cm3 (20℃)
【Usage】Used as an x-ray opaque penetrant in industrial radiography.
【Vapor Density】11
First Aid Measures
【Ingestion】Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. SPEED IS ESSENTIAL. A DOCTOR MUST BE NOTIFIED AT ONCE.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration.
【Skin】Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and Storage
【Storage】Store in a cool, dry place. Keep container closed when not in use. Corrosives area. Store protected from light and air. Store under an inert atmosphere.
【Handling】Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Do not allow contact with water. Avoid contact with air and sunlight. Discard contaminated shoes.
Hazards Identification
【Inhalation】May cause allergic respiratory reaction. Causes chemical burns to the respiratory tract.
【Skin】Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
【Eyes】Causes eye burns.
【Ingestion】May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. Chronic ingestion of iodides during pregnancy has resulted in fetal death, severe iter, and cretinoid appearance of the newborn.
【Hazards】Containers may explode when heated.
【EC Risk Phrase】R 34 50/53
【EC Safety Phrase】S 7/8 26 36/37/39 45 60 61
【UN (DOT)】1701
Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】Prolonged exposure to iodides may produce iodism in sensitive individuals. Exposure will include: skin rash, running nose and headache.
Fire Fighting Measures
【Flash Point】625℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】Combustible material: may burn but does not ignite ily.
Accidental Release Measures
【Small spills/leaks】Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stability and Reactivity
【Stability】Stable under normal temperatures and pressures.
【Incompatibilities】Strong oxidizing agents.
【Decomposition】Irritating and toxic fumes and gases, hydrogen iodide, toxic fumes of zinc oxide.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.
Transport Information
【UN Number】1701
【Hazard Class】6.1
【Packing Group】II